LMGP - Recherche Equipe NanoMAT

Wide & Ultra-Wide Bandgap Semiconducting Oxides

The Wide & Ultra-Wide Bandgap Semiconducting Oxides Research Line aims at developing and exploring the chemical synthesis of i) ZnO nanowires following the spontaneous and selective area growth approaches by chemical bath deposition (CBD) and ii) epitaxial Ga2O3 thin films by atomic layer deposition (ALD) and pulsed-liquid injection metal organic chemical vapor deposition (PLI-MOCVD). We are particularly interested in elucidating and controlling the nucleation and growth mechanisms, as well as the properties related to epitaxy, interfaces, and surfaces. We also determine and control the morphological, structural, and chemical properties of these objects, such as their intrinsic/extrinsic doping, polarity, the nature of involved defects, and surface-related effects. Advanced characterization techniques at the lab-scale (TEM, SEM/EDS, XRD, Raman spectroscopy, XPS) and at the synchrotron-scale (SAX, XRD) are regularly used to deepen our understanding of the structure-property relationship. Semiconducting heterostructures are also developed mainly for applications in the fields of piezoelectricity, UV photodetection, and power electronics. Finally, we are particularly interested in the multifactorial issues raised by the criticality of the raw materials used, as well as the environmental impact of our chemical deposition techniques assessed in the framework of green chemistry.

5 publications sélectionnées

[1] J. Villafuerte et al. Nano Energy 114, 108599 (2023)
Boosting the Piezoelectric Coefficients of Flexible Dynamic Strain Sensors Made of Chemically-Deposited ZnO Nanowires Using Compensatory Sb Doping

[2] G. Hector et al. Inorganic Chemistry 62, 7764-7771 (2023)
Chemical Bath Deposition of α-GaOOH with Tunable Morphology on Silicon Using the pH Adjustment

[3] A. Baillard et al. Small Structures 5, 2300540 (2024)
Significance of the Different Exposed Surfaces of ZnO Single Crystals and Nanowires on the Photocatalytic Activity and Processes

[4] M. Manrique et al. Small Structures 6, 2400534 (2025)
Incorporation and Compensatory Doping Processes of Cu into ZnO Nanowires Investigated at the Local Scale

[5] A. Séguret et al. Chemistry of Materials, in press (2025)
Atomic Layer Epitaxy of (002) κ-Ga2O3 on c-Plane Sapphire

Articles de revue

[1] J. Zuniga-Perez et al. Applied Physics Reviews 3, 041303 (2016)
Polarity in GaN and ZnO: Theory, Measurement, Growth, and Devices

[2] V. Consonni et al. Nanotechnology 30, 362001 (2019)
ZnO Nanowires for Solar Cells: A Comprehensive Review

[3] P. Gaffuri et al. Renewable and Sustainable Energy Reviews 143, 110869 (2021)
Potential Substitutes for Critical Materials in White LEDs: Technological Challenges and Market Opportunities

[4] V. Consonni et al. Nano Energy 83, 105789 (2021)
Polarity in ZnO Nanowires: A Critical Issue for Piezotronic and Piezoelectric Devices

Projets

ANR IMINEN (2023-2027, coordinateur)
Type : Agence Nationale de la Recherche, appel PRC
Titre : Elucider et contrôler les effets nanométriques dans les nanofils de ZnO pour les application piézoélectriques
Partenaires : Institut Néel (Grenoble), LTM (Grenoble), LETI (Grenoble), LGEF (Lyon)

ANR ALOFET (2024-2028, partenaire)
Type : Agence Nationale de la Recherche, appel PRC
Titre : Heterostructures de type AlN / Oxyde pour Transistors Améliorés par Polarisation
Partenaires : Institut Néel (Grenoble), CEA-IRIG-PHELIQS (Grenoble), CEA-IRIG-MEM (Grenoble)

MCDN SUSMATENER (2025-2028, partenaire)
Type : Horizon Europe, appel MCDN PRC
Titre : Sustainable Materials-By-Design for Renewable Energy
Partenaires : Universidade Nova de Lisboa (Lisboa) 
 

Collaborations nationales & internationales

  • CEA, IRIG, Grenoble
  • CEA, LETI, Grenoble
  • CROMA, Grenoble
  • GEMaC, Versailles
  • Institut Néel, Grenoble
  • LGEF, Lyon
  • LSI, Palaiseau
  • LTM, Grenoble
 
  • Université Aristote de Thessalonique, Grèce
  • Université de Leiden, Pays-Bas
  • Université de Lisbonne, Portugal
  • Université de Padoue, Italie
  • Université de Salerno, Italie
  • Université de Swansea, Pays de Galles