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Synthèse et propriétés de monocristaux, de poudres, films minces ou hétérostructures

Etudes à l'interface avec la matière biologique

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Publication A. Sekkat

Publié le 27 décembre 2021
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Communiqué du 27 décembre 2021 au 17 mai 2022

L'article intitulé "High performance encapsulation of transparent conductive polymers by spatial atomic layer deposition" a été publié dans Synthetic Metals

Ici vous trouverez l'article d'Abderrahime Sekkat
"Poly(3,4-ethylenedioxythiophene) (PEDOT) is a transparent conductive polymer widely used in flexible photonic and optoelectronic devices because of its excellent electrical and optical properties. However, its current range of applications is limited by its poor stability under high humidity and solar radiations. Encapsulation is an attractive solution to this problem and the development of a low-temperature and scalable deposition method is highly desirable. In this study, we report the use of spatial atomic layer deposition (SALD) to deposit ultrathin layers of ZnO, TiO2, and Al2O3. These nanolayers maintain the electrical performance of the conductive polymer and its high optical transmittance. The use of SALD ensures low-cost and flexible processing with pinhole-free high-quality coatings at atmospheric pressure and high-throughput. The present study is the first to investigate the effect of various multilayer metal oxide encapsulations on the long-term stability of PEDOT-based transparent conductive materials under solar radiations. We demonstrate finally that bilayer TiO2/Al2O3 and TiO2/ZnO coatings preserve the optoelectronic properties of three different PEDOT-based films, namely PEDOT:OTf (OTf = triflate), PEDOT:Sulf (Sulf = sulfate)and PEDOT:PSS (PSS = PolyStyreneSulfonate) films."
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mise à jour le 27 décembre 2021

  • Tutelle CNRS
  • Tutelle Grenoble INP
Université Grenoble Alpes